16 P + 15 HClO3 + 19 H2O → 5 HCl3 + 16 H3PO4

This is an oxidation-reduction (redox) reaction:

16 P0 - 80 e- → 16 PV (oxidation)

5 HI - 10 e- → 5 HIII (oxidation)

15 ClV + 90 e- → 15 Cl-I (reduction)

Reactants:

  • P
    • HClO3
      • Names: Chloric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Chloric(V) acid source: wikipedia, accessed: 2019-09-27, HClO3 source: wikidata, accessed: 2019-09-02
      • Appearance: Colourless solution source: wikipedia, accessed: 2019-09-27
    • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
      • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
      • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27

    Products:

    • HCl3
    • H3PO4
      • Names: Phosphoric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Orthophosphoric acid source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Phosphoric(V) acid source: wikidata, accessed: 2019-09-02
      • Appearance: Hygroscopic colourless crystals source: ICSC, accessed: 2019-09-04; Thick, colorless, odorless, crystalline solid. [Note: Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02