2 NaNO2 (aq) + H2SO4 (aq) Na2SO4 (aq) + NO (g) + NO2 (l) + H2O (l)

This is an oxidation-reduction (redox) reaction:

NIII + e- NII (reduction)

NIII - 1 e- NIV (oxidation)

NaNO2 is both an oxidizing and a reducing agent (disproportionation (dismutation)).

This is a gas evolution reaction, NO is the formed gas.

Reactants:

  • NaNO2
    • Names: Sodium nitrite source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, 7632-00-0 source: wikidata, accessed: 2019-09-02, E250 source: wikidata, accessed: 2019-09-02
    • Appearance: White or slightly yellowish solid source: wikipedia, accessed: 2019-09-27; Hygroscopic white-to-yellow solid in various forms source: ICSC, accessed: 2019-09-04
  • H2SO4Sulfuric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Oil of vitriol source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Sulfuric acid, concentrated (> 51% and < 100%) source: ICSC, accessed: 2019-09-04, H2SO4 source: wikidata, accessed: 2019-09-07
    • Appearance: Clear, colorless liquid source: wikipedia, accessed: 2019-09-27; Odourless colourless oily hygroscopic liquid source: ICSC, accessed: 2019-09-04; Colorless to dark-brown, oily, odorless liquid. [Note: Pure compound is a solid below 51°F. Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • Na2SO4
    • Names: Sodium sulfate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Sodium sulphate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Sulfate of sodium source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid | hygroscopic source: wikipedia, accessed: 2019-09-27; White hygroscopic solid in various forms source: ICSC, accessed: 2019-09-04
  • NONitrogen monoxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02, Oxidonitrogen(•) (additive) source: wikipedia, accessed: 2019-09-27
    • Other names: Nitric oxide source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02source: wikidata, accessed: 2019-09-02, Nitrogen(II) oxide source: wikipedia, accessed: 2019-09-27, Nitric oxide (radical) source: wikidata, accessed: 2019-09-02
    • Appearance: Colourless gas source: wikipedia, accessed: 2019-09-27; Colourless compressed gas source: ICSC, accessed: 2019-09-04; Colorless gas. [Note: Shipped as a nonliquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02
  • NO2Nitrogen dioxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Nitrogen(IV) oxide source: wikipedia, accessed: 2019-09-27, Deutoxide of nitrogen source: wikipedia, accessed: 2019-09-27, Nitrogen peroxide source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: Brown gas source: wikipedia, accessed: 2019-09-27; Reddish-brown gas or brown or yellow liquid with pungent odour source: ICSC, accessed: 2019-09-04; Yellowish-brown liquid or reddish-brown gas (above 70°F) with a pungent, acrid odor. [Note: In solid form (below 15°F) it is found structurally as N2O4.] source: NIOSH NPG, accessed: 2019-09-02
  • H2OWater, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27