NaHSO3 + 3 NaOH + 2 KMnO4 → 2 Na2MnO4 + K2SO4 + 2 H2O

This is an oxidation-reduction (redox) reaction:

2 MnVII + 2 e- → 2 MnVI (reduction)

SIV - 2 e- → SVI (oxidation)

KMnO4 is an oxidizing agent, NaHSO3 is a reducing agent.

Reactants:

  • NaHSO3 – Sodium hydrogen sulfite source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Sodium bisulfite source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02, E222 source: wikipedia, accessed: 2019-09-27, Sodium bisulphite source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27; Colourless-to-yellow liquid with characteristic odour source: ICSC, accessed: 2019-09-04; White crystals or powder with a slight odor of sulfur dioxide. source: NIOSH NPG, accessed: 2019-09-02
  • NaOH
    • Names: Sodium hydroxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Caustic soda source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Lye source: wikidata, accessed: 2019-09-02
    • Appearance: White, waxy, opaque crystals source: wikipedia, accessed: 2019-09-27; White hygroscopic solid in various forms source: ICSC, accessed: 2019-09-04; Colorless to white, odorless solid (flakes, beads, granular form). source: NIOSH NPG, accessed: 2019-09-02
  • KMnO4 – Potassium manganate(VII) source: wikipedia, accessed: 2019-09-27
    • Other names: Potassium permanganate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Chameleon mineral source: wikipedia, accessed: 2019-09-27, Condy's crystals source: wikipedia, accessed: 2019-09-27
    • Appearance: Purplish-bronze-gray needles | magenta–rose in solution source: wikipedia, accessed: 2019-09-27; Dark purple crystals source: ICSC, accessed: 2019-09-04

Products:

  • Na2MnO4
  • K2SO4
    • Names: Potassium sulfate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Potassium sulphate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Dipotassium sulfate source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27; Colourless-to-white crystals source: ICSC, accessed: 2019-09-04
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27