3 NO₂ (l) + H₂O (l) → 2 HNO₃ (aq) + NO (g)

This is an oxidation-reduction (redox) reaction:

NO₂ is both an oxidizing and a reducing agent (disproportionation (dismutation)).

Reactants:

• NO₂ – Nitrogen dioxide
  • Other names: Nitrogen(IV) oxide , Deutoxide of nitrogen , Nitrogen peroxide ... show moreNO2 , NO2(.) , Dinitrogen tetroxide (see notes) , Nitrogen tetroxide , Dinitrogen tetroxide show less
  • Appearance: Brown gas ; Reddish-brown gas or brown or yellow liquid with pungent odour ; Yellowish-brown liquid or reddish-brown gas (above 70°F) with a pungent, acrid odor. [Note: In solid form (below 15°F) it is found structurally as N2O4.]
• H₂O – Water, oxidane
  • Other names: Water (H2O) , Hydrogen hydroxide (HH or HOH) , Hydrogen oxide ... show moreDihydrogen monoxide (DHMO) (systematic name) , Hydrogen monoxide , Dihydrogen oxide , Hydric acid , Hydrohydroxic acid , Hydroxic acid , Hydrol , Μ-oxido dihydrogen , Κ1-hydroxyl hydrogen(0) show less
  • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas

Products:

• HNO₃ – Nitric acid
  • Other names: Aqua fortis , Spirit of niter , Eau forte ... show moreHydrogen nitrate , Acidum nitricum , Nitric acid (> 70% in water) , Fuming nitric acid , Engravers acid , HONO2 , Red fuming nitric acid , RFNA , White fuming nitric acid (WFNA) show less
  • Appearance: Colorless, yellow or red fuming liquid ; Colourless-to-yellow liquid with pungent odour ; Colorless, yellow, or red, fuming liquid with an acrid, suffocating odor. [Note: Often used in an aqueous solution. Fuming nitric acid is concentrated nitric acid that contains dissolved nitrogen dioxide.]
• NO – Nitrogen monoxide , Oxidonitrogen(•) (additive)
  • Other names: Nitric oxide , Nitrogen(II) oxide , Nitric oxide (radical) ... show moreMononitrogen monoxide , (.)NO , EDRF , Nitrogen monooxide , [NO] , Oxido de nitrogeno(ii) , NO(.) , Oxido nitrico , Stickstoff(ii)-oxid , NO , Oxyde azotique , Oxyde nitrique , Stickstoffmonoxid , Nitrosyl , (NO)(.) , Monoxido de nitrogeno , Endothelium-derived relaxing factor , Nitroxide radical , Nitroxyl , Nitrosyl radical , Hydroxyamine , Nitrogen oxide , Nitrogen protoxide , Nitrosyl hydride , Nitric Oxide show less
  • Appearance: Colourless gas ; Colourless compressed gas ; Colorless gas. [Note: Shipped as a nonliquefied compressed gas.]