H2SeO3 + 2 H2S → Se + 3 H2O + 2 S

This is an oxidation-reduction (redox) reaction:

SeIV + 4 e- → Se0 (reduction)

2 S-II - 4 e- → 2 S0 (oxidation)

H2SeO3 is an oxidizing agent, H2S is a reducing agent.

Reactants:

  • H2SeO3 – Selenous acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Selenic(IV) acid source: wikipedia, accessed: 2019-09-27
    • Other names: Selenious acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, [SeO(OH)2] source: wikidata, accessed: 2019-09-02, Selenige Säure source: wikidata, accessed: 2019-09-02, Monohydrated selenium dioxide source: ICSC, accessed: 2019-09-04
    • Appearance: White hygroscopic crystals source: wikipedia, accessed: 2019-09-27; Colourless hygroscopic crystals source: ICSC, accessed: 2019-09-04
  • H2S – Hydrogen sulfide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: D source: wikipedia, accessed: 2019-09-27, Ihydrogen monosulfide|Dihydrogen sulfide|Sewer gas|Sulfane|Sulfurated hydrogen|Sulfureted hydrogen|Sulfuretted hydrogen|Sulfur hydride|Hydrosulfuric acid|Hydrothionic acid|Thiohydroxic acid|Sulfhydric acid}} source: wikipedia, accessed: 2019-09-27, Hydrosulfuric acid source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: Colorless gas source: wikipedia, accessed: 2019-09-27; Colourless compressed liquefied gas with characteristic odour of rotten eggs source: ICSC, accessed: 2019-09-04; Colorless gas with a strong odor of rotten eggs. [Note: Sense of smell becomes rapidly fatigued & can NOT be relied upon to warn of the continuous presence of H2S. Shipped as a liquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • Se
    • Names: Selenium source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Se source: wikidata, accessed: 2019-09-07, Selen source: wikidata, accessed: 2019-09-07
    • Appearance: Grey solid in various forms source: ICSC, accessed: 2019-09-04; Amorphous or crystalline, red to gray solid. [Note: Occurs as an impurity in most sulfide ores.] source: NIOSH NPG, accessed: 2019-09-02
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27
  • S
    • Names: Sulfur source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04, S source: wikidata, accessed: 2019-09-07, Sulphur source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04
    • Appearance: Yellow solid in various forms source: ICSC, accessed: 2019-09-04