4 CH3OH (aq) + 3 Br2 (aq) + S (s) → 4 CH3Br (g) + H2SO4 (aq) + 2 HBr (aq)

This is an oxidation-reduction (redox) reaction:

6 Br0 + 6 e- → 6 Br-I (reduction)

S0 - 6 e- → SVI (oxidation)

Br2 is an oxidizing agent, S is a reducing agent.

Reactants:

  • CH3OH – Methanol source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Carbinol source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Columbian spirits source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02, Hydroxymethane source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Appearance: Colorless liquid source: wikipedia, accessed: 2019-09-27; Colourless liquid with characteristic odour source: ICSC, accessed: 2019-09-04; Colorless liquid with a characteristic pungent odor. source: NIOSH NPG, accessed: 2019-09-02
  • Br2
    • Names: Bromine source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Molecular bromine source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: Fuming red-to-brown liquid with pungent odour source: ICSC, accessed: 2019-09-04; Dark reddish-brown, fuming liquid with suffocating, irritating fumes. source: NIOSH NPG, accessed: 2019-09-02
  • S
    • Names: Sulfur source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04, S source: wikidata, accessed: 2019-09-07, Sulphur source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04
    • Appearance: Yellow solid in various forms source: ICSC, accessed: 2019-09-04

Products:

  • CH3Br
    • Names: Methyl bromide source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, MeBr source: wikidata, accessed: 2019-09-02, CH3Br source: wikidata, accessed: 2019-09-02
    • Appearance: Odourless colourless compressed liquefied gas source: ICSC, accessed: 2019-09-04; Colorless gas with a chloroform-like odor at high concentrations. [Note: A liquid below 38°F. Shipped as a liquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02
  • H2SO4 – Sulfuric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Oil of vitriol source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Sulfuric acid, concentrated (> 51% and < 100%) source: ICSC, accessed: 2019-09-04, H2SO4 source: wikidata, accessed: 2019-09-07
    • Appearance: Clear, colorless liquid source: wikipedia, accessed: 2019-09-27; Odourless colourless oily hygroscopic liquid source: ICSC, accessed: 2019-09-04; Colorless to dark-brown, oily, odorless liquid. [Note: Pure compound is a solid below 51°F. Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02
  • HBr – Hydrogen bromide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Bromane source: wikipedia, accessed: 2019-09-27source: wikipedia, accessed: 2019-09-27
    • Other names: Hydrobromic acid source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04, Hydronium bromide source: wikipedia, accessed: 2019-09-27, HBr source: wikidata, accessed: 2019-09-02
    • Appearance: Colorless gas source: wikipedia, accessed: 2019-09-27; Colorless/faint yellow liquid source: wikipedia, accessed: 2019-09-27; Colourless compressed liquefied gas with pungent odour source: ICSC, accessed: 2019-09-04; Colorless gas with a sharp, irritating odor. [Note: Shipped as a liquefied compressed gas. Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02