2 NaOH + NO₂ + NO → 2 Na(NO₂) + H₂O

This is an acid-base reaction (neutralization): NaOH is a base, NO₂ is an acid.

This is an oxidation-reduction (redox) reaction:

NO is a reducing agent, NO₂ is an oxidizing agent (synproportionation (comproportionation)).

Reactants:

• NaOH
  • Names: Sodium hydroxide , Caustic soda , Lye ... show moreSoda lye , Sodium hydrate , NaOH , White caustic , Lye [Sodium hydroxide] show less
  • Appearance: White, waxy, opaque crystals ; White hygroscopic solid in various forms ; Colorless to white, odorless solid (flakes, beads, granular form).
• NO₂ – Nitrogen dioxide
  • Other names: Nitrogen(IV) oxide , Deutoxide of nitrogen , Nitrogen peroxide ... show moreNO2 , NO2(.) , Dinitrogen tetroxide (see notes) , Nitrogen tetroxide , Dinitrogen tetroxide show less
  • Appearance: Brown gas ; Reddish-brown gas or brown or yellow liquid with pungent odour ; Yellowish-brown liquid or reddish-brown gas (above 70°F) with a pungent, acrid odor. [Note: In solid form (below 15°F) it is found structurally as N2O4.]
• NO – Nitrogen monoxide , Oxidonitrogen(•) (additive)
  • Other names: Nitric oxide , Nitrogen(II) oxide , Nitric oxide (radical) ... show moreMononitrogen monoxide , (.)NO , EDRF , Nitrogen monooxide , [NO] , Oxido de nitrogeno(ii) , NO(.) , Oxido nitrico , Stickstoff(ii)-oxid , NO , Oxyde azotique , Oxyde nitrique , Stickstoffmonoxid , Nitrosyl , (NO)(.) , Monoxido de nitrogeno , Endothelium-derived relaxing factor , Nitroxide radical , Nitroxyl , Nitrosyl radical , Hydroxyamine , Nitrogen oxide , Nitrogen protoxide , Nitrosyl hydride , Nitric Oxide show less
  • Appearance: Colourless gas ; Colourless compressed gas ; Colorless gas. [Note: Shipped as a nonliquefied compressed gas.]

Products:

• Na(NO₂)
• H₂O – Water, oxidane
  • Other names: Water (H2O) , Hydrogen hydroxide (HH or HOH) , Hydrogen oxide ... show moreDihydrogen monoxide (DHMO) (systematic name) , Hydrogen monoxide , Dihydrogen oxide , Hydric acid , Hydrohydroxic acid , Hydroxic acid , Hydrol , Μ-oxido dihydrogen , Κ1-hydroxyl hydrogen(0) show less
  • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas