AsH3 + 8 HNO3 → H3AsO4 + 8 NO2 + 4 H2O
This is an oxidation-reduction (redox) reaction:
As-III - 8 e- → AsV (oxidation)
8 NV + 8 e- → 8 NIV (reduction)
AsH3 is a reducing agent, HNO3 is an oxidizing agent.
Reactants:
- AsH3 – Arsenic trihydride
, Arsane
, Trihydridoarsenic
- HNO3 – Nitric acid
- Other names: Aqua fortis
, Spirit of niter
, Eau forte
- Appearance: Colorless, yellow or red fuming liquid
; Colourless-to-yellow liquid with pungent odour
; Colorless, yellow, or red, fuming liquid with an acrid, suffocating odor. [Note: Often used in an aqueous solution. Fuming nitric acid is concentrated nitric acid that contains dissolved nitrogen dioxide.]
- Other names: Aqua fortis
Products:
- H3AsO4 – Arsenic acid, arsoric acid
- NO2 – Nitrogen dioxide
- Other names: Nitrogen(IV) oxide
, Deutoxide of nitrogen
, Nitrogen peroxide
- Appearance: Brown gas
; Reddish-brown gas or brown or yellow liquid with pungent odour
; Yellowish-brown liquid or reddish-brown gas (above 70°F) with a pungent, acrid odor. [Note: In solid form (below 15°F) it is found structurally as N2O4.]
- Other names: Nitrogen(IV) oxide
- H2O – Water, oxidane