3 As2O3 (s) + 2 KBrO3 (aq) + 2 HCl (aq) → 3 As2O5 (aq) + 2 HBr (aq) + 2 KCl (aq)

This is an oxidation-reduction (redox) reaction:

2 BrV + 12 e- → 2 Br-I (reduction)

6 AsIII - 12 e- → 6 AsV (oxidation)

KBrO3 is an oxidizing agent, As2O3 is a reducing agent.

Reactants:

  • As2O3 – Diarsenic trioxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Arsenic trioxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Arsenic(III) oxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Arsenic sesquioxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27; White lumps or crystalline powder source: ICSC, accessed: 2019-09-04
  • KBrO3 – Potassium bromate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Potassium bromate(V) source: wikipedia, accessed: 2019-09-27, Bromic acid source: wikipedia, accessed: 2019-09-27, Potassium salt source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline powder source: wikipedia, accessed: 2019-09-27; White crystals or powder source: ICSC, accessed: 2019-09-04
  • HCl – Chlorane source: wikipedia, accessed: 2019-09-27, Hydrogen chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Hydrochloric acid source: wikipedia, accessed: 2019-09-27source: NIOSH NPG, accessed: 2019-09-02, M source: wikipedia, accessed: 2019-09-27, Uriatic acid source: wikipedia, accessed: 2019-09-27
    • Appearance: Colorless, transparent liquid, fumes in air if concentrated source: wikipedia, accessed: 2019-09-27; Colorless gas source: wikipedia, accessed: 2019-09-27; Colourless compressed liquefied gas with pungent odour source: ICSC, accessed: 2019-09-04; Colorless to slightly yellow gas with a pungent, irritating odor. [Note: Shipped as a liquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • As2O5
    • Names: Diarsenic pentoxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Arsenic(V) oxide source: wikipedia, accessed: 2019-09-27, Arsenic oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White hygroscopic powder source: wikipedia, accessed: 2019-09-27; White hygroscopic powder source: ICSC, accessed: 2019-09-04
  • HBr – Hydrogen bromide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Bromane source: wikipedia, accessed: 2019-09-27source: wikipedia, accessed: 2019-09-27
    • Other names: Hydrobromic acid source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04, Hydronium bromide source: wikipedia, accessed: 2019-09-27, HBr source: wikidata, accessed: 2019-09-02
    • Appearance: Colorless gas source: wikipedia, accessed: 2019-09-27; Colorless/faint yellow liquid source: wikipedia, accessed: 2019-09-27; Colourless compressed liquefied gas with pungent odour source: ICSC, accessed: 2019-09-04; Colorless gas with a sharp, irritating odor. [Note: Shipped as a liquefied compressed gas. Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02
  • KCl
    • Names: Potassium chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Sylvite source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Muriate of potash source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Appearance: White crystalline solid source: wikipedia, accessed: 2019-09-27; Colourless hygroscopic crystals source: ICSC, accessed: 2019-09-04