3 N2O4 (l) + KBr (aq) + 6 KOH (aq) → KBrO3 (aq) + 6 KNO2 (aq) + 3 H2O (l)

This is an oxidation-reduction (redox) reaction:

Br-I - 6 e- → BrV (oxidation)

6 NIV + 6 e- → 6 NIII (reduction)

KBr is a reducing agent, N2O4 is an oxidizing agent.

Reactants:

  • N2O4 – Dinitrogen tetraoxide source: wikipedia, accessed: 2019-09-27
    • Other names: Dinitrogen tetroxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, [N(NO2)O2] source: wikidata, accessed: 2019-09-02, Nitrogen tetroxide source: wikidata, accessed: 2019-09-02
    • Appearance: Colourless liquid, orange gas source: wikipedia, accessed: 2019-09-27
  • KBr
    • Names: Potassium bromide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, KBr source: wikidata, accessed: 2019-09-02, Kaliumbromid source: wikidata, accessed: 2019-09-02
    • Appearance: White solid source: wikipedia, accessed: 2019-09-27
  • KOH – Potassium hydroxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Caustic potash source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Lye source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Potash lye source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02
    • Appearance: White solid, deliquescent source: wikipedia, accessed: 2019-09-27; White hygroscopic solid in various forms source: ICSC, accessed: 2019-09-04; Odorless, white or slightly yellow lumps, rods, flakes, sticks, or pellets. [Note: May be used as an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • KBrO3 – Potassium bromate source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04
    • Other names: Potassium bromate(V) source: wikipedia, accessed: 2019-09-27, Bromic acid source: wikipedia, accessed: 2019-09-27, Potassium salt source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline powder source: wikipedia, accessed: 2019-09-27; White crystals or powder source: ICSC, accessed: 2019-09-04
  • KNO2
    • Names: Potassium nitrite source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Nitrous acid potassium salt source: ICSC, accessed: 2019-09-04
    • Appearance: White or slight yellow solid | deliquescent source: wikipedia, accessed: 2019-09-27; White-to-yellow deliquescent solid in various forms source: ICSC, accessed: 2019-09-04
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27