3 K3AsS3 + 26 HNO3 → 3 K3AsO4 + 9 H2SO4 + 26 NO + 4 H2O

This is an oxidation-reduction (redox) reaction:

3 AsIII - 6 e- → 3 AsV (oxidation)

9 S-II - 72 e- → 9 SVI (oxidation)

26 NV + 78 e- → 26 NII (reduction)

K3AsS3 is a reducing agent, K3AsS3 is a reducing agent, HNO3 is an oxidizing agent.

Reactants:

  • K3AsS3
  • HNO3 – Nitric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Aqua fortis source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02, Spirit of niter source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02, Eau forte source: wikipedia, accessed: 2019-09-27
    • Appearance: Colorless, yellow or red fuming liquid source: wikipedia, accessed: 2019-09-27; Colourless-to-yellow liquid with pungent odour source: ICSC, accessed: 2019-09-04; Colorless, yellow, or red, fuming liquid with an acrid, suffocating odor. [Note: Often used in an aqueous solution. Fuming nitric acid is concentrated nitric acid that contains dissolved nitrogen dioxide.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • K3AsO4
    • Names: Tripotassium arsenate source: wikidata, accessed: 2019-09-03
  • H2SO4 – Sulfuric acid source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: NIOSH NPG, accessed: 2019-09-02
    • Other names: Oil of vitriol source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02, Sulfuric acid, concentrated (> 51% and < 100%) source: ICSC, accessed: 2019-09-04, H2SO4 source: wikidata, accessed: 2019-09-07
    • Appearance: Clear, colorless liquid source: wikipedia, accessed: 2019-09-27; Odourless colourless oily hygroscopic liquid source: ICSC, accessed: 2019-09-04; Colorless to dark-brown, oily, odorless liquid. [Note: Pure compound is a solid below 51°F. Often used in an aqueous solution.] source: NIOSH NPG, accessed: 2019-09-02
  • NO – Nitrogen monoxide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02, Oxidonitrogen(•) (additive) source: wikipedia, accessed: 2019-09-27
    • Other names: Nitric oxide source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02source: wikidata, accessed: 2019-09-02, Nitrogen(II) oxide source: wikipedia, accessed: 2019-09-27, Nitric oxide (radical) source: wikidata, accessed: 2019-09-02
    • Appearance: Colourless gas source: wikipedia, accessed: 2019-09-27; Colourless compressed gas source: ICSC, accessed: 2019-09-04; Colorless gas. [Note: Shipped as a nonliquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02
  • H2O – Water, oxidane source: wikipedia, accessed: 2019-09-27
    • Other names: Water (H2O) source: wikipedia, accessed: 2019-09-27, Hydrogen hydroxide (HH or HOH) source: wikipedia, accessed: 2019-09-27, Hydrogen oxide source: wikipedia, accessed: 2019-09-27
    • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas source: wikipedia, accessed: 2019-09-27