5 Na₂SO₃ + 2 KMnO₄ + H₂O → Mn₂O₂ + 5 Na₂SO₄ + 2 KOH

This is an oxidation-reduction (redox) reaction:

KMnO₄ is an oxidizing agent, Na₂SO₃ is a reducing agent.

Reactants:

• Na₂SO₃ – Sodium sulfite
  • Other names: Sodium sulphite , Hypo clear (photography) , E221 ... show moreNa2SO3 , Anhydrous sodium sulfite , Sodium sulfite anhydrous , Sulfurous acid, disodium salt , Dried sodium sulfite , Disodium sulfite show less
  • Appearance: White solid ; White crystals or powder
• KMnO₄ – Potassium manganate(VII)
  • Other names: Potassium permanganate , Chameleon mineral , Condy's crystals ... show morePermanganate of potash Hypermangan , Permanganic acid potassium salt show less
  • Appearance: Purplish-bronze-gray needles | magenta–rose in solution ; Dark purple crystals
• H₂O – Water, oxidane
  • Other names: Water (H2O) , Hydrogen hydroxide (HH or HOH) , Hydrogen oxide ... show moreDihydrogen monoxide (DHMO) (systematic name) , Hydrogen monoxide , Dihydrogen oxide , Hydric acid , Hydrohydroxic acid , Hydroxic acid , Hydrol , Μ-oxido dihydrogen , Κ1-hydroxyl hydrogen(0) show less
  • Appearance: White crystalline solid, almost colorless liquid with a hint of blue, colorless gas

Products:

• Mn₂O₂
• Na₂SO₄
  • Names: Sodium sulfate , Sodium sulphate , Sulfate of sodium ... show moreThenardite (mineral) , Glauber's salt (decahydrate) , Sal mirabilis (decahydrate) , Mirabilite (decahydrate mineral) , Disodium sulfate , Anhydrous sodium sulfate , Sodium sulfate anhydrous , Sodium sulfate, anhydrous , Sodium sulphate anhydrous , Sodium sulphate, anhydrous , Sulfuric acid disodium salt, anhydrous , Disodium sulphate , Salt cake , Na2SO4 , Sulfuric acid disodium salt show less
  • Appearance: White crystalline solid | hygroscopic ; White hygroscopic solid in various forms
• KOH – Potassium hydroxide
  • Other names: Caustic potash , Lye , Potash lye ... show morePotassia , Potassium hydrate , KOH , E525 , Potassium lye , Lye [Potassium hydroxide] show less
  • Appearance: White solid, deliquescent ; White hygroscopic solid in various forms ; Odorless, white or slightly yellow lumps, rods, flakes, sticks, or pellets. [Note: May be used as an aqueous solution.]