FeCl3 + H2S → H2Cl + FeCl2 + S

This is an oxidation-reduction (redox) reaction:

S-II - 2 e- → S0 (oxidation)

2 HI + e- → 2 H1/2 (reduction)

FeIII + e- → FeII (reduction)

H2S is a reducing agent, H2S is an oxidizing agent, FeCl3 is an oxidizing agent.

Reactants:

  • FeCl3 – Iron(III) chloride source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04, Iron trichloride source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04
    • Other names: {{ubl source: wikipedia, accessed: 2019-09-27, Ferric chloride source: wikidata, accessed: 2019-09-02, Ferric chloride (anhydrous) source: ICSC, accessed: 2019-09-04
    • Appearance: Green-black by reflected light; purple-red by transmitted light; yellow solid as hexahydrate; brown as {{abbr|aq.|aqueous}} solution source: wikipedia, accessed: 2019-09-27; Black-to-brown hygroscopic crystals source: ICSC, accessed: 2019-09-04
  • H2S – Hydrogen sulfide source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04source: NIOSH NPG, accessed: 2019-09-02
    • Other names: D source: wikipedia, accessed: 2019-09-27, Ihydrogen monosulfide|Dihydrogen sulfide|Sewer gas|Sulfane|Sulfurated hydrogen|Sulfureted hydrogen|Sulfuretted hydrogen|Sulfur hydride|Hydrosulfuric acid|Hydrothionic acid|Thiohydroxic acid|Sulfhydric acid}} source: wikipedia, accessed: 2019-09-27, Hydrosulfuric acid source: wikidata, accessed: 2019-09-02source: NIOSH NPG, accessed: 2019-09-02
    • Appearance: Colorless gas source: wikipedia, accessed: 2019-09-27; Colourless compressed liquefied gas with characteristic odour of rotten eggs source: ICSC, accessed: 2019-09-04; Colorless gas with a strong odor of rotten eggs. [Note: Sense of smell becomes rapidly fatigued & can NOT be relied upon to warn of the continuous presence of H2S. Shipped as a liquefied compressed gas.] source: NIOSH NPG, accessed: 2019-09-02

Products:

  • H2Cl
  • FeCl2 – Iron(II) chloride source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04, Iron dichloride source: wikipedia, accessed: 2019-09-27source: ICSC, accessed: 2019-09-04
    • Other names: Ferrous chloride source: wikipedia, accessed: 2019-09-27source: wikidata, accessed: 2019-09-02source: ICSC, accessed: 2019-09-04, Rokühnite source: wikipedia, accessed: 2019-09-27, [FeCl3] source: wikidata, accessed: 2019-09-02, FeCl3 source: wikidata, accessed: 2019-09-02
    • Appearance: Tan solid (anhydrous) | Pale green solid (di-tetrahydrate) source: wikipedia, accessed: 2019-09-27; White-to-light-green hygroscopic crystals source: ICSC, accessed: 2019-09-04
  • S
    • Names: Sulfur source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04, S source: wikidata, accessed: 2019-09-07, Sulphur source: wikidata, accessed: 2019-09-07source: ICSC, accessed: 2019-09-04
    • Appearance: Yellow solid in various forms source: ICSC, accessed: 2019-09-04